That was info presented by BKVP in 2009, so I don't know if it still holds. Interesting nonetheless. This chart, from the link above, is hard to read but seems to indicate that the cat needs more temp to light off as it gets older, but when it lights off, still works well:
"When you burn wood, a bunch of VOC's are released as well as potassium magnate. In many older cat stoves, the potassium magnate attacked the substrate material, mullite or cooderite and caused the substrate to fall apart. (by the way, cat stoves destroy 100% of all VOC's when the cat is over 500F also called active.)
Combustion by products lay over the top of the surface area over time and the precious metals cannot make contact with the smoke. That in turn starts the plugging that can plague cat stoves when used improperly. (Wet wood, trash burning etc.)
Under a magnifying glass you would see the surface area of the combustor looks like the surface of the moon, tons of craters. This vastly increases total surface area and allows for more complete burning of the smoke.
When you do the major cleaning, which involves the distilled water and vinegar, the acids remove the deposited materials and once again expose the precious metals to the smoke. In essence, you can definitely rejuvenate a combustor by this process. Not likely to 100% new, but quite a bit and get some extended life from the combustor. Many owners tell us they have two combustors. One in use and the other cleaned, wrapped with new gasket and stored in a zip lock bag and ready to go. Every 6-8 years, they swap them out, clean the dirty one, regasket and store away for a another few years.
I have a King in my home and I must tell you I have never removed the combustor, not in 10 years. It burns like the day it was new and I have gone so far as to thermocouple the unit in my home to check temps and other specs. Dry wood, hot fires one and week and no chemicals are the most important conditions to assure a long life. (Keep the door gasket tension snug at all times as well.)
When a combustor is on it's last leg you will know it. The stove just will not "breath" and the wood will not burn to completion. So how do you get them to last, burn 18% or lower moisture content fuel. Never throw in wood with ice and snow and cause huge temperature swings to the ceramic, leave the door cracked as little as necessary, room air hitting the face of the combustor can damage it over time. Clean it with a soft brush and maybe vacuum at the end of each season."
I have never seen anything about an EPA required lifetime of 6 years
This is more 2009 info from BKVP but I think it still holds true.
"
Combustor Warranty
The Environmental Protection Agency requires that each stove manufacturer provide a 6-year prorated warranty on original combustors. Depending upon stove design, combustors can last or remain effective as little as 2 years (burning seasons) or up to 10 years or more. Each combustor returned to the stove manufacturer is in turn shipped back to the original supplier for testing. Without question, although small in number, the vast majority of the combustors failed due to thermal shock. Thermal shock is generally the result of rapid temperature changes (such as loading hot stove full of snow or ice laden wood) or excessive draft.
Less than .4% of all OEM combustors are replaced in the first three years of the warranty coverage. Less than 10% of all OEM combustors are replaced during the EPA mandated 6 year warranty. These figures are based upon data provided by OEM providers and resellers of combustors."
BKVP has been consistent in saying that cats will live longer in BKs than in many other stoves, due to running more controlled cat temps in a BK, versus some other stoves.
What about when you close the bypass and run the air wide open for a half hour? I think your cat temp goes pretty high, does it not?
I don't think we're seeing much evidence of catalyst depletion, the assumed failure mode, when discussing hours or years of operation. I think we're seeing more evidence of cat plugging, in combustors with plenty of life left in them.
I suspect very few combustors are depleted in these short periods of less than three years full-time use (e.g. < 10,000 hours). I suspect most are deformed from overheating, flame impingement, thermal shock, or ash plugging.
My SIL went through a couple diesel-foils that only lasted a couple years, but I think she ran 'em hot. That's why, since I saw that, I've tried to run my cats moderately.