Ashful
Minister of Fire
My Jotul Firelights used to have the same behavior. I believe it was because there is some point in a long slow burn, usually in the second hour for me, where the wood gets baked enough that it begins producing volatile gasses at a much higher rate. This is just more fuel for the cat, and the cat temp goes up. One solution was to open the air enough to burn more of these gasses in primary flame, which can often bring down combustor temperature, but I always worried this was putting me into a run-away situation on those old Jotuls.The cat probe picture above is well after the initial high burn and there are no flames in the fire box. It was at that thermostat setting for about an hour when I noticed how high the cat probe was.
My experience with my BK's (so far) is that the cat is large enough that I don't see these crazy high probe temperatures when the wood outgassing peaks like this. After all, the Ashford combustor is double the size of the Jotul Firelight 12 combustor, and its a smaller firebox.
All interesting stuff for some folks here, but of little actual use to you, I guess. I'd want to somehow verify that cat probe is correct (eg. pick up a Condar probe of same length), to see how hot it's actually getting, and see what BKVP says about it.