Here's a thought.
Without looking at your plumbing diagram, the zone circ / circs for the baseboards, if you have something like a standard 007, you could try replacing that with an ECM circ with fixed temp sensing. Then the circ sensor would go on the baseboard's return pipe / header and be set to something like 130 -140 F.
If it fits your application, it would be one of the easiest changes you could make. At cold start, the circ would max to achieve HW return of 130 F, but would quickly ramp down as setpoint is met. So you would have a variable load, high when you need it in the beginning so the boiler starts out firing hard, then quickly lightens up but stays on at a lower load, giving time for the boiler to turn down.
I cannot understand how the DHW tank does not become fully mixed with boiler water at the end of the cycle. But this way, the boiler circ should be flowing lots more than the load ECM circ, so the tank should see that flow. Sizewise, the tank should be invisible to the boiler, like putting an ice cube in a pot of boiler macaroni.
You do need to take out the loading unit, disconnect the zones / DHW tank, and fire the boiler, as making steam, condensate, popping the relief valve, seems to be the only thing that will keep you happy.
Without looking at your plumbing diagram, the zone circ / circs for the baseboards, if you have something like a standard 007, you could try replacing that with an ECM circ with fixed temp sensing. Then the circ sensor would go on the baseboard's return pipe / header and be set to something like 130 -140 F.
If it fits your application, it would be one of the easiest changes you could make. At cold start, the circ would max to achieve HW return of 130 F, but would quickly ramp down as setpoint is met. So you would have a variable load, high when you need it in the beginning so the boiler starts out firing hard, then quickly lightens up but stays on at a lower load, giving time for the boiler to turn down.
I cannot understand how the DHW tank does not become fully mixed with boiler water at the end of the cycle. But this way, the boiler circ should be flowing lots more than the load ECM circ, so the tank should see that flow. Sizewise, the tank should be invisible to the boiler, like putting an ice cube in a pot of boiler macaroni.
You do need to take out the loading unit, disconnect the zones / DHW tank, and fire the boiler, as making steam, condensate, popping the relief valve, seems to be the only thing that will keep you happy.