Jan Pijpelink
Minister of Fire
Dry NaOH does not hurt anything. Only if dissolved in water at high concentration.Speaking of which, NaOH is very alkaline and used as a drain cleaner. It does eat steel.
The moral of the story is that baking soda may be a good idea to put out a chimney fire, but don't put it in your stove unless you really need to.
And like bholler says, for an overfire you can just open the door.