What I'm wondering is will the life of the cat be shortened if its operated (within the proper limits of the stove with the acceptable fuel/moisture content) on high (100%) indefinitely vs one that is operated in the same manner but at a lower heat output (say 75%?).I would think that any time the cat is lit, it's using life. When you burn on high, how brightly is the cat glowing, compared to when you burn on a medium or low setting? What about cat probe readings at the different air settings?
The questions really has to do with reactivity of the cat and is its life shortened by running the stove harder but within the limits specified by the manufacture.
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I think they are saying that because it will minimize smoke roll-out into the room in setups where the draft is weaker. With my stove and stack, I can open the door anytime and get no smoke....might have to open it more slowly in certain situations, though.

Besides, it's harder to pull air through the cat than through an open bypass, and smoke in the box will also be routed forward, so you will get more smoke roll-out.