Yes. I have been known to run the stove a little hotter just to look at the flames and to boost the temp in the stove room quickly but then to set the stove output back so that I don't overheat the room but also so that I can get the full 24 hour burntime. The cat stays active and burns clean so long as it lights off in the beginning.
These stoves have such a low output in the lower temp ranges that you can set it and forget it. Really, if you are overheating on the low settings, it is probably too warm outside for a fire. You can then resort to the "pulse and glide" style of burning where you let the stove cool between fires like you would with a non-cat except the glide periods will be a day or two since it will be so warm outside.
I must always run mine on zero, it cranks out so much heat I have to open windows in the house. The cat just goes nuts with a full load of wood, I don't get down to lower output until about 2/3 the burn time. I cannot lower the output by lowering the thermostat until most of the wood is gone -
I almost always get 24 hours of burn time, but I wish I could lower the heat output - just will not happen.
Cat is always clean, and brushing the chimney after 3 or 4 full cords yields about 2 cups of creosote in the chimney -