Are you sure you are not cavitating one of the pumps? Any flow restrictions upstream of the circs?
Cavitation forms, and will continue to form vapor pockets, not to be confused with air bubbles. Vapor pockets can form even in a system that has been purger 100% air free.
Vapor pockets form when you drop the fluid pressure below the vapor pressure, this can happen at the eye, or inlet to the circ under some conditions. So the key is to make sure the SUCTION side of the circ has enough static pressure to prevent this condition.
And the hotter the fluid the more apt to create or cause cavitation. Vapor pressure of water at 140F is 2.9 psia, at 200F it around 10psi. So be sure you have at least 10 psi at the circ inlet. This is the key to why so many OWF destroy their pumps frequently, not enough pressure in an open vessel to provide the vapor pressure to prevent cavitation.
Idronics 16 will be about pump sizing, selection, and troubleshootring.
Did you use a Caleffi 281 ThermoBloc? It has a gravity gate (check valve) inside. it ships with a screw locking it closed that needs to be removed for gravity circulation function.
Tips for avoiding cavitation
Run system pressure as high as possible (practical)
fluid temperature as low as possible
expansion tank at the suction of the circ pumps ALWAYS
mount circ pump as low as possible in piping, maximizes static pressure at the suction
no flow restriction devices on the suction side, valves, checks, mixers, etc
12" of straight pipe is ideal, not always possible on the suction side
Microbubble type air separators, the iron, scoop type vents are best for light boat anchors