ABMax24
Minister of Fire
It takes a certain temperature for CO to ignite. Generally all of the other volatiles in the wood burn at lower temps so if you burn the CO everything else is long gone. If the firebox temp is less than the minimum, the CO goes right up the stack. Even if that minimum temperature is met there has to be enough turbulence for the CO molecules to directly interact with oxygen (close is not good enough they need to touch). Cold air coming in cools down the temps so preheating it keeps the temps up. That usually means a hot fast fire to get full combustion. All a cat does is reduce the ignition temperature of the volatile gases and the intermediate combustion gas CO. Once the reaction happens there is a blend of hot gasses that have to interact with heat exchangers to transfer some hat sink like a room, a block of mass or tank of water. Ideally this heat exchange is done through a series of heat exchangers with low mass. If its a clean burn there is no creosote but there is water vapor mostly from the water in the wood and some trivial amount formed in the combustion process. If that vapor is condensed there is a bit more energy to be grabbed (1000 btus per pound of water that runs through the stove). The device to do that is called a condensing heat exchanger. If there is low temp demand for warm water the stack temps can be brought down to very low temps to the point where this a fan needed to get good dispersion out of the stack. During start up and shut down there can be corrosive gases that make it past full combustion and they in combination with water vapor can make conditions acidic so the heat exchanger is usually made out of stainless and has fairly open clearances and a way of cleaning it.
Is there a point at which NOx is formed in wood combustion in high enough concentrations to require mitigation?
As you've stated the obvious answer for clean wood combustion is to get the gases hot enough (I believe I've read 1600F is sufficient) with enough excess oxygen to progress the reaction to completion, but does this eventually produce NOx like an internal combustion engine does?
If it does I would imagine mitigation of the NOx becomes difficult, gasoline engines have the advantage of constantly cycling between lean and rich combustion and by using a 3-way catalytic converter effectively convert NOx and the unburnt hydrocarbons and residuals to nothing more than N2, H20 and CO2. I would think wood combustion would be more like that of a diesel engine, which is always oxygen rich, removing the simple 3-way cat as a mitigation method, which then leads toward more complex systems like Urea and an SCR which is used on the current generation of diesel engines.