Well the starting and ending materials are the same (smoke + O2) -> (CO2 +H2O) but the cat enables the reaction to happen at a lower temperature.Not sure. I know typical combustion requires fuel and air. But a cat is partly a chemical reaction to the gasses the wood produces when it smolders. When you cut air to the burning fire you create more smoke/gasses. Im sure air is required for the cat process but I would guess less is required then for normal combustion?
So yes I probably choked the fire too fast and created a puff of smoke that made the cat temperature shoot up. But then shouldn't it gradually calm down after that, even with excess air? I'm just thinking out loud here