Some questions and thoughts. With just the wood circ running maybe a Grundfos 15-58 on speed 2, 12 gpm of flow. How many gpms go through the first storage? How many through the second? what regulates that flow?
If the wood circ and the load circ run at the same time, and they are the same pump, you now have the two circs in series, about 12 gpm at 20 feet of had available through the zones. I would suggest a pressure activated bypass valve be piped in to shed some of that head or those zone valves will see some very high velocity, potentially. Not knowing what is in those baseboard circuits for pipe diametse, length, fittings, etc. Depending on the zone valve type and brand they may not have enough shut off pressure to handle those pumps in series. You may bleed through the valves under some conditions. Although it is unknown how much goes through the tanks and how much to the load circuits. Ideally flowsetters would be installed on the two tanks to "set" that flow rate. Then you would have some stable numbers to design the rest of the system around.
Really no need for two expansion tanks and connection points. You'll just confuse the hydraulics by having two PONPC's. I'd suggest an air purger before the load circ. It's the highest temperature point and the best place to remove air from the system. Also connect the, or multiple, expansion tank and the fill valve at that connection. The point in the system where you install the expansion tank becomes the PONPC (point of no pressure change) in the system. The circs reference that point in the system. Read Dan Holohans "Pumping Away" book to learn more about PONPC, etc. It's also the place where the fill valve should connect.
I'm not a huge fan of this piping with so many unknowns, I'm sure it will heat and move energy.
The bubbles are some changes I feel would help
1 A weighted flow check above wood boiler to limit flow when wood pump is off, and the load circ is on trying to draw from storage.
2 flowsetters on the two tanks to determine and adjust the amount of gpm going to them. A ball valve would work and use your hand to "adjust by feel
3 Add a good air removal device, like a Caleffi Discal just before the load circ
4 connect the expansion tank(s) at the bottom of that air removal device, along with the fill valve and appropiate backflow device
5 add a properly sized PAB (pressure activated bypass valve) downstream of the load circ, tied into the return. Include a ball valve to aid purging
6 Install a Webstone ball/ purge valve just before the boiler protection valve. With this one valve you could purge each loop one by one via the manual operation of zone valves
7 It might be nice to have a means to take the storage out of the loop and feed the boiler directly to the loads, unless you can assure the correct flow to the loads under the various conditions
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