I took apart a vent valve this afternoon and saw a lot of black goo in there. I've seen the same thing when I did some plumbing work on a cold water line. It doesn't clean off with soap, but did with a citrus based solvent. We have well water, but it's not that hard and we use a softener. I figure it's bacteriological. We do get a whiff of sulfur every once in a while in our drinking water, but nothing much.