What a great amount of information...let me start off by expressing my thanks for your (and every other posters), time helping with this.
Building is 4500 sf, uninsulated Quonset style warehouse. uninsulated slab is 6" on pig wire over compacted sand (I think there was a vapor barrier in there somewhere), with 1/2" lines attached to the pig wire. I recall the lines being approx. 18" apart.
When setting up the loop lengths, diameters, spacing, pumps etc., I relied on the same person who sold me the Stove...thus I didn't insulate under the loops (water table is pretty low), used 1/2" (why pay for 3/4" when you don't need it), 500' loops (experience has shown the old 'limits' to lengths are incorrect), and a Taco 0011 to push the water to the warehouse (again, it's all you need for your circumstances...comments are those of the stove seller).
You mention a Taco 007 and 009. I'm using one Taco 0011 about 3' from the heat exchanger that pumps to the warehouse AND pumps the 3500' of 1/2" in the slab (I was told 1 pump does it all)(I do have a spare Grunsfos 15-58 F4 on the shelf).
So...with some items indelibly fixed, here's what I can change...
I can insulated the walls of the warehouse...probably take a season or two to get it done however.
I can upsize the supply lines to 1-1/4 (Ouch)...at least I can use the existing 3/4" stuff for future expansion to a greenhouse, kiln, or mobile home.
I can upsize the pump.
I can put in a storage device...with propane backup?
You mention using a straight thermostatic mix valve (in the warehouse), to limit the temp going out to the slab...I was recently told to install a mixing valve between the exchanger and the 007, not out at the warehouse...do these provide the same result e.g. keeping the water temp at the stove up?
When it comes to storage/backup heat...Easiest around here would probably be a propane fired - water heater. Any thoughts on this? (I can possibly do this quicker than insulating the warehouse as it's full of stuff and will be hard to access other that a bit at a time).
Next, I'll get to working on the pics of the creosote problems.
Regards, Scotty