The hottest part of a cat stove during the cruise is the top of the stove around the cat. I'd wager that when you are ramping up a fresh load, with the heat and radiation of big flame in the box, the sides may be quite a bit hotter than at cruise. I can't really test this theory on my stove because of the buffering/lag effect of two layers of stone..but steel stove guys should be able to verify weather this is the case.
I'm not sure we can ascertain the color of the smoke from Rangerbait's picture on the internet. We'd have to be there to say for sure. But to me, it looks kinda heavy and dirty. White, wispy smoke is steam, gray or blue smoke is wood smoke. This creo smoke has an almost brown look to it. When I have a bad 'smoke out the hood' episode (doesn't happen every time) after a long, low burn, there's a thick, billowing cloud of foul-smelling creo smoke blanketing the area like a heavy fog. I mean, birds are falling out of the trees. I think this is the condensed, concentrated creo on the walls of the stove burning off..hours worth of deposits being burned off in a relatively short period of time. Yes, later in the burn you will still get a little creo smell but I think that even though the majority has burned off the walls, I think the creo-burning continues at a lower level. It's a much worse smell than you would get just burning a few splits at your fire pit.
So if you have company coming over, or the neighbors are out, make sure you burn out your stove beforehand, then throw on some Black Cherry splits and you'll have them saying "What a lovely fragrance, we should get one of those wood-burners!"
Remember, all sides of the bk other than the cat dome are either glass or insulated in some way. Just part of the very rear of some models is actual exposed steel. So perhaps your problems are Woodstock problems and not bk problems. I never have brown smoke, just white, blue, or clear.