Dragging this up before the season starts, but I see the air wash igniting off gassing as well. However, I see STT above 750 F and single wall surface temps of 500+ (so 1000+ internal) when this happens. Basically I see secondaries occur then eventually the air wash causes secondary combustion as well and the STT increases a lot when this occurs. I am confident that I do
not have sufficient draft for my stove. My stove calls for 0.06-0.1" wc (hearthstone shelburn 8372); minimum chimney height of 16.5' from ST if setup in a rear exit configuration, 6" flue. I had a 5.5" uninsulated liner in a 16' external chimney with a rear exit setup. I haven't tested the draft, but I get smoke rollout when I open the door regardless of the stage of the fire with the bypass open. Currently upgrading the chimney system to fix this.
My thought process for why this was occurring; as I closed the primary air the total volume of gases going up the chimney decreased. This caused the flue to begin to cool (not insulated), which reduced the draft causing a reduction in velocity of the gases. Even though the STT and gasses were hot there just wasn't enough volume to keep the flue warm. Everything still went up the chimney, but there wasn't a lot of movement, so the stove got hot, the wood off gassed and any air introduced ignited it.
Do you have any issues with smoke rollout from the stove? The scenario sounds similar, except you're not seeing high STT. You're measuring STT on the ST and not the heat shield correct?
According to the manual for your stove the minimum chimney height is 12ft above the ST. Are you sure that the Mark II 25 is zeroed out correctly? (manual link:
https://dwyer-inst.com/PDF_files/D_58.pdf) The accuracy of the reading for that gauge is +/- 0.09" wc (+/-3% full-scale of 3"wc). So it's not a very accurate gauge for measuring wood stove draft. Something like a Dwyer 2000-00 would perform better; it's full-scale is 0.25"wc and has an accuracy of 0.01"wc (+/-4% FS).
How does your stove perform with the longer chimney? I skimmed the posts and I couldn't confirm if you were having this issue with the primary air igniting secondaries at taller chimney heights.