I woke up 12:00 on Sunday night to the sound of my smoke detectors going off and the sound of water and steam gushing. Went and opened my basement door and was overwhelmed with steam and couldn't see a darn thing. I grabbed a flashlight and headed down to the boiler the temp gauge was maxed out and pressure was at 0. I shut the primary and secondary air to slow down the burn. I found the pex that ran above my flue pipe had exploded and that's where the steam and water was leaking from. I isolated that zone and then confirmed that there was still some water in the boiler. I manually opened the relief valve and pulled out a pipe plug just to be safe. The boiler was still making steam because there was no pressure. I started to fill it back up real slow because I didn't want to temp shock the steel. Meanwhile my wife is running around vacuming and mopping up the boiler water that had gone into several basement rooms. After about 1/2 hr the boiler was full again cooled off and holding pressure. I Checked the fire and it was still going but now just a bed of coals. We finished cleaning up for the night and let the boiler run in oil mode. So I guess you never want PEX above the flu pipe even if it was 20" above it's still not enough under certain conditions.