It should go away soon. Perhaps you are smelling dust that got knocked down on the insert and is getting heated up? Or dust on the inside of the convection chamber of the insert that settled on top of the firebox as the block-off plate was installed?
All of those are possible. Who knows. I definitely did not go through and clean the firebox with a fine comb after the plate was installed so there certainly is dust and debris from the impact of drilling into the brick to pre tap the Tapcons.
Ultimately it’s ok to have the mineral wool insulated against the insert though?