Only thing I can think is that when the cat housing glows, it distorts and opens up some leaks where smoke gets past the cat.
How active a burn do you usually keep going? Medium to large flame in the box?
I have a Dutchwest with a similar setup, cast iron cat flame shield below the cat, then the 8x2" round cat is wrapped in interam gasket and drops into a "cup" that holds it. To get that cast iron shield glowing, cat has to be orange and I'd have to have pretty strong flame going in the box. If I have a cat-only burn, no flame, the cat shield doesn't glow. I never saw any cat probe temp above 1200-1300. The Buck 91 would try to push above 1500 on occasion, no flame in the box, but I would nip that in the bud when it happened.
Do you need flame going in the box to be able to heat your place, or will a cat-only burn do the job?
What kind of wood do you generally burn? If it's lightweight wood that burns faster and feeds the cat more volatiles, quicker, that will cause the cat to burn hotter. Dense woods like White Oak or Black Locust burn and gas slower, so are less of a problem in that regard.
With your new cat, was there interam gasket supplied, that wrapped around the cat? Is it an OEM cat? Some cats are wrapped in interam, then a stainless band is wrapped on top to hold the interam gasket in place. I'd guess the cat was made by Firecat (Applied Ceramics)...?
Yeah, but you're BK guys. You're commanded to keep your hands off things like stove air control/cat temps (no numbers on the probe dial,) let the stove run itself, and not worry your pretty little heads about such things. 😏 Unless you have a probe in your stoves, cat temps are a moot point for you.