Welcome to the boards Catfish, hope we can help you out... You will get a lot of benefit from reading as much of the past threads that look interesting as you can stand :lol: then we can help fill in the parts you still have questions on...
As a very basic minimum...
There are two basic approaches with a gasification wood boiler, one more expensive and complex initially, but FAR more efficient, especially in the non-heating season, the other easier, but less efficient.
The easy way is to just slap a wood or wood / oil burner in place of the oil burner - as you said, sounds like you might need a new chimney, otherwise nothing to terrible in the way of added plumbing. The way it will work, is that you build a fire, and the house demand draws heat until it's satisfied, at which point the boiler will go into "idle" mode, where the air is shut off almost totally, keeping just enough to (hopefully) keep the fire burning. When the demand returns, the air turns back on, the fire heats back up, and the cycle repeats. While this works, it is very inefficient, can make for lots of smoke when the boiler comes off idle, and is not a real optimal approach.
The preferred method is to use thermal storage - usually a large tank of water (500 or more gallons) plumbed alongside the wood boiler. With storage, the boiler is run flat out, at it's maximum burn rate until the fire is done - any heat that isn't used to heat the demand is used to heat the storage tank. After the fire goes out, the demand draws from the heat stored in the tank until the tank temperature drops down, at which point you build another fire in the boiler. There are a lot of aspects to sizing the storage tank and boiler, but when properly done, most people will find they only need to fire up the boiler about once a week in the summer if all they are making is DHW. As the weather gets colder, you will need to fire more often, until you reach the point during the coldest temperatures where you will need to fire just about as often with storage as you would have without it. The other big advantage of storage is that it makes it very easy to tie in additional heat sources like solar, which can totally eliminate your need to run the boiler in the summer.
Hope this helps.
Gooserider