How dirty did your boiler used to get? Did it use to make a lot of creosote within the unit itself? Require a lot of cleaning?
That chimney doesn't look all that high - I suspect you might not have enough draft (I think you also mentioned the fire is hard to start?). That together with how cold it is is likely condensing the creosote & also might be affecting the quality of the burn itself. You also mentioned the stove holding heat well overnight - that also might be a sign that it is not burning hard enough to burn off the nasties within. i.e., might be choked down. And if the boiler used to get dirty, it might have been condensing a lot of the nasties before they got to the chimney.
Was the creosote there before the makeup air pipe thing was installed? It might be cooling things even more and causing more condensation.
I'm also not familiar with either that boiler or that stove so not 100% in what I'm saying.
EDIT: I'm also curious what it looks like inside the bottom of the chimney. I think I see a cleanout at the bottom of the wall, just right of the creosote? If there is cool basement air getting in around that panel thing, that will also help condense creosote, and reduce the draft. Was your boiler forced draft by chance?
OK - Let's see if i can answer everything.
-The Clay liner is 8 x 8. The chimney has two liners, one for the fireplace & one for the wood stove.
-The clean out is about 2' below where the stovepipe goes into the chimney. The clean out has a door to seal it inside, and outside the door to the plate covering the clean out is stuffed with insulation. (The creosote seems to be leaking under the door, under the insulation and running down the wall.
- There are no open block cores inside the clean out.
- The chimney total height is 18' outside the house, the wood stove is in the basement, so the chimney for the wood stove is a little higher than 18'.
- Haven't tested the pipe temperature during the burn. We have now put the thermometer on the pipe and will check it next time..
- Our original Prairie Farm wood boiler (which was used day and night anytime it was under 40 deg., did not have a buildup of creosote. The flues (tubes through the water cabinet) were "punched" about every 2 weeks, along with the stove pipe, & the interior of the stove cleaned. What came off was very fine ash, no build up. Cleaning the whole chimney never resulted much more than a fine ash.
- there was no creosote before the makeup air was installed, but it was installed within 2 weeks of the stove going in, as it was hard to start.
- The clean out someone mentioned seeing at ground level to the right of the creosote is for the upstairs fireplace, which has it's own flue.
We cleaned the pipes & checked the chimney today. When we opened the clean out door, the only creosote showing was evidently where it flowed out on the floor of the clean out. There was only a few small "chimney shovels" of ash from the cleaning of the chimney, and an inspection of the chimney itself showed no buildup. It's a puzzle. Any ideas welcome. We have re-sealed the door which is about a foot into the wall behind the clean out door. Hopefully the new seal will help.